Alloy-Free Band Gap Tuning across the Visible Spectrum
dc.contributor.author | Makin RA | |
dc.contributor.author | York K | |
dc.contributor.author | Durbin SM | |
dc.contributor.author | Senabulya N | |
dc.contributor.author | Mathis J | |
dc.contributor.author | Clarke R | |
dc.contributor.author | Feldberg N | |
dc.contributor.author | Miska P | |
dc.contributor.author | Jones CM | |
dc.contributor.author | Deng Z | |
dc.contributor.author | Williams L | |
dc.contributor.author | Kioupakis E | |
dc.contributor.author | Reeves RJ | |
dc.date.accessioned | 2020-02-04T00:04:49Z | |
dc.date.available | 2020-02-04T00:04:49Z | |
dc.date.issued | 2019 | en |
dc.date.updated | 2019-07-12T03:56:40Z | |
dc.description.abstract | We present evidence, from theory and experiment, that ZnSnN2 and MgSnN2 can be used to match the band gap of InGaN without alloying—by exploiting cation disorder in a controlled fashion. We base this on the determination of S, the long-range order parameter of the cation sublattice, for a series of epitaxial thin films of ZnSnN2 and MgSnN2 using three different techniques: x-ray diffraction, Raman spectroscopy, and in situ electron diffraction. We observe a linear relationship between S2 and the optical band gap of both ZnSnN2 (1.12–1.98 eV) and MgSnN2 (1.87–3.43 eV). The results clearly demonstrate the correlation betweencontrolledheterovalentcationorderingandtheopticalbandgap,whichappliestoabroadgroupof emerging ternary heterovalent compounds and has implications for similar trends in other material properties besides the band gap. | en |
dc.identifier.citation | Makin RA, York K, Durbin SM, Senabulya N, Mathis J, Clarke R, Feldberg N, Miska P, Jones CM, Deng Z, Williams L, Kioupakis E, Reeves RJ Alloy-Free Band Gap Tuning across the Visible Spectrum. Physical Review Letters. 122(25). | en |
dc.identifier.doi | https://doi.org/10.1103/physrevlett.122.256403 | |
dc.identifier.issn | 0031-9007 | |
dc.identifier.issn | 1079-7114 | |
dc.identifier.uri | http://hdl.handle.net/10092/17960 | |
dc.language | English | |
dc.language.iso | en | |
dc.publisher | American Physical Society (APS) | en |
dc.subject.anzsrc | Field of Research::02 - Physical Sciences | en |
dc.title | Alloy-Free Band Gap Tuning across the Visible Spectrum | en |
dc.type | Journal Article | en |
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