Dimensionality Variation in Dinuclear Cu(II) Complexes of a Heterotritopic Pyrazolate Ligand

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dc.contributor.authorHawes, C.S.
dc.contributor.authorKruger, P.E.
dc.date.accessioned2016-01-21T22:47:16Z
dc.date.available2016-01-21T22:47:16Z
dc.date.issued2014en
dc.description.abstractTwo new Cu(II) complexes of the ligand 3-carboxy-5-(2-pyridyl)-1H-pyrazole, H2L1, have been prepared and structurally characterized and found to be comprised of a similar [M2L2] dimer motif. Subtle variation in the synthetic conditions allowed isolation of two metal complexes: [Cu2L12(MeOH)2], 1, a discrete dimer linked by hydrogen bonding interactions in the solid state, and poly-[Cu2L12], 2, a polymeric material where the dimer motif is linked by carboxylate bridges to give an extended two-dimensional sheet. The selective isolation of each phase by careful synthetic control highlights the subtlety and importance of the underlying synthetic conditions.en
dc.identifier.citationHawes, C.S., Kruger, P.E. (2014) Dimensionality Variation in Dinuclear Cu(II) Complexes of a Heterotritopic Pyrazolate Ligand. Crystals, 4(1), pp. 32-41.en
dc.identifier.doihttps://doi.org/10.3390/cryst4010032
dc.identifier.urihttp://hdl.handle.net/10092/11684
dc.language.isoen
dc.publisherUniversity of Canterbury. Chemistryen
dc.rights.urihttps://hdl.handle.net/10092/17651en
dc.subjectheterocyclesen
dc.subjectcrystallographyen
dc.subjectmetallosupramolecular chemistryen
dc.subjectcrystal engineeringen
dc.subject.anzsrcField of Research::03 - Chemical Sciences::0303 - Macromolecular and Materials Chemistry::030302 - Nanochemistry and Supramolecular Chemistryen
dc.titleDimensionality Variation in Dinuclear Cu(II) Complexes of a Heterotritopic Pyrazolate Liganden
dc.typeJournal Article
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