X-Ray Crystallographic Study of Copper(II), Cobalt(II) and Silver(I) Complexes of Ligands Containing Two Oxine Subunits Linked by Xylylene Spacer Groups
dc.contributor.author | Al-Mandhary, M.R.A. | |
dc.contributor.author | Steel, P.J. | |
dc.date.accessioned | 2007-08-17T02:02:55Z | |
dc.date.available | 2007-08-17T02:02:55Z | |
dc.date.issued | 2004 | en |
dc.description.abstract | X-Ray crystal structures are reported for six transition metal complexes of the ligands 1,2-bis(8-quinolyloxymethyl)benzene (3) and 1,3-bis(8-quinolyloxymethyl)benzene (4). In three mononuclear copper(II) and cobalt(II) complexes ligand 3 acts as a chelating ligand, with either N,O,N’-tridentate or N,O,O’,N’-tetradentate coordination. A novel binuclear silver(I) complex of 3 is shown to be stabilised by a number of weak metal-ligand contacts and multiple intramolecular π−π stacking interactions. In two binuclear copper(II) nitrate complexes of 4, the ligand adopts very different bridging modes of coordination. | en |
dc.identifier.citation | Al-Mandhary, M.R.A., Steel, P.J. (2004) X-Ray Crystallographic Study of Copper(II), Cobalt(II) and Silver(I) Complexes of Ligands Containing Two Oxine Subunits Linked by Xylylene Spacer Groups. European Journal of Inorganic Chemistry, 2004, pp. 329-334. | en |
dc.identifier.uri | http://hdl.handle.net/10092/383 | |
dc.language.iso | en | |
dc.publisher | University of Canterbury. Chemistry. | en |
dc.rights.uri | https://hdl.handle.net/10092/17651 | en |
dc.subject | N,O ligands | en |
dc.subject | copper | en |
dc.subject | cobalt | en |
dc.subject | silver | en |
dc.subject | bridging ligands | en |
dc.subject.marsden | Fields of Research::250000 Chemical Sciences::259900 Other Chemical Sciences::259901 Organometallic chemistry | en |
dc.subject.marsden | Fields of Research::250000 Chemical Sciences::250300 Organic Chemistry::250399 Organic chemistry not elsewhere classified | en |
dc.title | X-Ray Crystallographic Study of Copper(II), Cobalt(II) and Silver(I) Complexes of Ligands Containing Two Oxine Subunits Linked by Xylylene Spacer Groups | en |
dc.type | Journal Article |
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