Preparation of open and closed forms of the lvt network with Cu(II) complexes of structurally related 1,2-diazole ligands
dc.contributor.author | Hawes, C.S. | |
dc.contributor.author | Kruger, P.E. | |
dc.date.accessioned | 2016-01-21T22:34:20Z | |
dc.date.available | 2016-01-21T22:34:20Z | |
dc.date.issued | 2014 | en |
dc.description.abstract | Reported here are the synthesis and structural characterisation of two topologically related coordination polymers: [Cu(L1)(CH3CONH2)], 1, and [Cu(L2)(NMP)]$0.5NMP$0.5H2O, 2, (NMP ¼ N-methylpyrrolidinone) prepared from 1H-indazole-3-carboxylic acid, H2L1, and 1H-pyrazole-3-carboxylic acid, H2L2, respectively. Both 1 and 2 crystallise in the tetragonal space group I41/a and form 3-dimensional coordination polymers described by the lvt topology, in which [Cu2L2] dimers form four-connected nodes linked through carboxylate groups. Within 1 the presence of a Cu-bound acetamide molecule (formed in situ by the solvothermal hydration of acetonitrile) propagates hydrogen bonding between dimer units that, combined with the steric bulk of the indazole fragment, yield a closed (non-porous) framework. In 2, however, Cu-bound NMP, which does not participate in hydrogen bonding, coupled with the less bulky nature of the pyrazole-backbone, gives rise to an open framework of an otherwise isostructural network. | en |
dc.identifier.citation | Hawes, C.S., Kruger, P.E. (2014) Preparation of open and closed forms of the lvt network with Cu(II) complexes of structurally related 1,2-diazole ligands. RSC Advances, 4, pp. 15770–15775. | en |
dc.identifier.doi | https://doi.org/10.1039/c4ra02147a | |
dc.identifier.uri | http://hdl.handle.net/10092/11683 | |
dc.language.iso | en | |
dc.publisher | University of Canterbury. Chemistry | en |
dc.rights.uri | https://hdl.handle.net/10092/17651 | en |
dc.subject.anzsrc | Field of Research::03 - Chemical Sciences | en |
dc.title | Preparation of open and closed forms of the lvt network with Cu(II) complexes of structurally related 1,2-diazole ligands | en |
dc.type | Journal Article |
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