Transferability of crystal-field parameters for rare-earth ions in  Y$_2$SiO$_5$ tested by Zeeman spectroscopy

Jobbitt NL; Patchett SJ; Alizadeh Y; Reid MF; Wells J-PR; Horvath SP; Longdell JJ; Ferrier A; Goldner P

Transferability of crystal-field parameters for rare-earth ions in Y$_2$SiO$_5$ tested by Zeeman spectroscopy

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1811.00158v1.pdf (323.31 KB)

Type of content

Journal Article

UC permalink

http://hdl.handle.net/10092/16263

Date

2018

Authors

Jobbitt NL

Patchett SJ

Alizadeh Y

Reid MF

Wells J-PR

Horvath SP

Longdell JJ

Ferrier A

Goldner P

Abstract

Zeeman spectroscopy is used to demonstrate that phenomenological crystal-field parameters determined for the two $C1$ point-group sites in Er $3+$ :Y $2$ SiO $5$ may be transferred to other ions. The two crystallographic six- and seven-coordinate substitutional sites may be distinguished by comparing the spectra with crystal-field calculations.

ANZSRC fields of research

Field of Research::03 - Chemical Sciences::0302 - Inorganic Chemistry

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Science: Journal Articles

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