Temperature dependent infrared absorption, crystal-field and intensity analysis of Ce3+ Doped LiYF4

dc.contributor.authorWells, J-P.R.
dc.contributor.authorHorvath, S.P.
dc.contributor.authorReid, M.F.
dc.date.accessioned2016-01-26T01:24:06Z
dc.date.available2016-01-26T01:24:06Z
dc.date.issued2015en
dc.description.abstractInfrared absorption has been used to determine the crystal-field levels of the 2F7=2 excited multiplet of trivalent cerium doped into scheelite structure LiYF4 single crystals. A crystal-field analysis well accounts for a total of six experimentally observed energy levels and the ground state g-values as previously determined by electron paramagnetic resonance, whilst intensity simulations confirm the experimentally assigned level symmetries. Temperature dependent spectral line broadening measurements highlight the importance of coupling to low frequency phonon modes of the YF8 tetrahedron.en
dc.identifier.citationWells, J-P.R., Horvath, S.P., Reid, M.F. (2015) Temperature dependent infrared absorption, crystal-field and intensity analysis of Ce3+ Doped LiYF4. Optical Materials, 47, pp. 30-33.en
dc.identifier.doihttps://doi.org/10.1016/j.optmat.2015.06.046
dc.identifier.urihttp://hdl.handle.net/10092/11722
dc.language.isoen
dc.publisherUniversity of Canterbury. Physics and Astronomyen
dc.rights.urihttps://hdl.handle.net/10092/17651
dc.subjectLiYF4en
dc.subjectspectroscopyen
dc.subjectcrystal-field analysesen
dc.subjectphonon scattering processesen
dc.subject.anzsrcFields of Research::51 - Physical sciences::5102 - Atomic, molecular and optical physics::510203 - Nonlinear optics and spectroscopyen
dc.titleTemperature dependent infrared absorption, crystal-field and intensity analysis of Ce3+ Doped LiYF4en
dc.typeJournal Article
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