Extending Phenomenological Crystal-Field Methods to C1 Point-Group Symmetry: Characterization of the Optically Excited Hyperfine Structure of Er1673+:Y2SiO5

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dc.contributor.authorHorvath SP
dc.contributor.authorRakonjac JV
dc.contributor.authorChen Y-H
dc.contributor.authorLongdell JJ
dc.contributor.authorGoldner P
dc.contributor.authorWells J-PR
dc.contributor.authorReid MF
dc.date.accessioned2019-11-07T23:56:00Z
dc.date.available2019-11-07T23:56:00Z
dc.date.issued2019en
dc.date.updated2019-08-01T20:33:21Z
dc.description.abstractWe show that crystal-field calculations for C1 point-group symmetry are possible, and that such calculations can be performed with sufficient accuracy to have substantial utility for rare-earth based quantum information applications. In particular, we perform crystal-field fitting for a C1-symmetry site in 167Er3þ∶Y2SiO5. The calculation simultaneously includes site-selective spectroscopic data up to 20 000 cm−1, rotational Zeeman data, and ground- and excited-state hyperfine structure determined from high-resolution Raman-heterodyne spectroscopy on the 1.5 μm telecom transition. We achieve an agreement of better than 50 MHz for assigned hyperfine transitions. The success of this analysis opens the possibility of systematically evaluating the coherence properties, as well as transition energies and intensities, of any rare-earth ion doped into Y2SiO5.en
dc.identifier.citationHorvath SP, Rakonjac JV, Chen Y-H, Longdell JJ, Goldner P, Wells J-PR, Reid MF Extending Phenomenological Crystal-Field Methods to C1 Point-Group Symmetry: Characterization of the Optically Excited Hyperfine Structure of Er1673+:Y2SiO5. Physical Review Letters. 123(5).en
dc.identifier.doihttps://doi.org/10.1103/physrevlett.123.057401
dc.identifier.issn0031-9007
dc.identifier.issn1079-7114
dc.identifier.urihttp://hdl.handle.net/10092/17574
dc.languageEnglish
dc.language.isoen
dc.publisherAmerican Physical Society (APS)en
dc.subject.anzsrcField of Research::03 - Chemical Sciences::0306 - Physical Chemistry (incl. Structural)en
dc.titleExtending Phenomenological Crystal-Field Methods to C1 Point-Group Symmetry: Characterization of the Optically Excited Hyperfine Structure of Er1673+:Y2SiO5en
dc.typeJournal Articleen
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