X-ray crystal structures of discrete and polymeric chiral silver complexes of monoterpenoid alkenes

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dc.contributor.authorCottam, J.R.A.
dc.contributor.authorSteel, P.J.
dc.date.accessioned2007-08-17T00:49:07Z
dc.date.available2007-08-17T00:49:07Z
dc.date.issued2006en
dc.description.abstractX-ray crystal structures are reported for five silver(I) complexes of four monoterpenoid alkenes. Discrete mononuclear complexes of the chiral alkenes (1S)-(-)-α-pinene and (1S)-(-)-ß-pinene with silver perchlorate and silver hexafluorophosphate are described. The achiral diene γ-terpinene forms a discrete mononuclear adduct with silver hexafluorophosphate and a two-dimensional polymeric network structure with silver triflate. The chiral diene (R)-(+)-limonene forms a one-dimensional chiral coordination polymer with silver hexafluorophosphate. In all structures the silver atom is η2-bonded to the carbon–carbon bond(s) of the monoterpene with slightly longer bond distances to the more substituted carbon of the alkene moiety.en
dc.identifier.citationCottam, J.R.A., Steel, P.J. (2006) X-ray crystal structures of discrete and polymeric chiral silver complexes of monoterpenoid alkenes. Journal of Organometallic Chemistry, 691(10), pp. 2286-2290.en
dc.identifier.doihttps://doi.org/10.1016/j.jorganchem.2005.11.046
dc.identifier.issn0022-328X
dc.identifier.urihttp://hdl.handle.net/10092/380
dc.language.isoen
dc.publisherUniversity of Canterbury. Chemistry.en
dc.rights.urihttps://hdl.handle.net/10092/17651en
dc.subjectsilveren
dc.subjectalkeneen
dc.subjectcrystal structureen
dc.subjectbridging ligandsen
dc.subjectself-assemblyen
dc.subject.marsdenFields of Research::250000 Chemical Sciences::250300 Organic Chemistryen
dc.subject.marsdenFields of Research::250000 Chemical Sciences::250100 Physical Chemistry (Incl. Structural)::250105 Structural chemistryen
dc.subject.marsdenFields of Research::250000 Chemical Sciences::259900 Other Chemical Sciences::259901 Organometallic chemistryen
dc.titleX-ray crystal structures of discrete and polymeric chiral silver complexes of monoterpenoid alkenesen
dc.typeJournal Article
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