Model Discrimination of Radical Desorption Kinetics in Emulsion Polymerisation
dc.contributor.author | Fellows, C.M. | |
dc.contributor.author | Murison, R.D. | |
dc.contributor.author | Russell, G.T. | |
dc.date.accessioned | 2011-08-24T23:57:43Z | |
dc.date.available | 2011-08-24T23:57:43Z | |
dc.date.issued | 2011 | en |
dc.description.abstract | Analysis of published experimental data on monomeric radical diffusion in the emulsion polymerisation of styrene shows that it can be quantitatively described equally well by non-equilibrium diffusion from particles, where all parameters are derived from properties of the discrete phase, or by steady-state diffusion where all parameters are derived from properties of the continuous phase. The non-equilibrium model better describes an observed experimental trend to a reduced desorption rate coefficient at higher weight fraction of polymer in the particles. The theoretical upper bound of the non-equilibrium model is also higher than the theoretical upper bound of the steady-state model allowing fits to experimental data which must be discarded as anomalous in the continuous phase model. | en |
dc.identifier.citation | Fellows, C.M., Murison, R.D., Russell, G.T. (2011) Model Discrimination of Radical Desorption Kinetics in Emulsion Polymerisation. Macromolecular Theory and Simulations, 20(6), pp. 425-432. | en |
dc.identifier.doi | https://doi.org/10.1002/mats.201100044 | |
dc.identifier.issn | 1521-3919 | |
dc.identifier.uri | http://hdl.handle.net/10092/5375 | |
dc.language.iso | en | |
dc.publisher | University of Canterbury. Chemistry | en |
dc.rights.uri | https://hdl.handle.net/10092/17651 | en |
dc.subject | emulsion polymerisation | en |
dc.subject | kinetics (polym.) | en |
dc.subject.anzsrc | Field of Research::03 - Chemical Sciences | en |
dc.subject.anzsrc | Field of Research::03 - Chemical Sciences::0303 - Macromolecular and Materials Chemistry | en |
dc.title | Model Discrimination of Radical Desorption Kinetics in Emulsion Polymerisation | en |
dc.type | Journal Article |
Files
Original bundle
1 - 1 of 1
Loading...
- Name:
- 12632386_Model Discrimination of Radical Desorption Kinetics in Emulsion Polymerisation 8.pdf
- Size:
- 471.71 KB
- Format:
- Adobe Portable Document Format