Electrochemistry and UV/visible spectroscopy of phosphino-substituted bis(η⁵-indenyl)iron(II) complexes

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dc.contributor.authorCurnow, O.J.
dc.contributor.authorFern, G.M.
dc.contributor.authorJenkins, E.M.
dc.date.accessioned2007-11-27T21:45:36Z
dc.date.available2007-11-27T21:45:36Z
dc.date.issued2006en
dc.description.abstractSix phosphino-functionalized diindenyl ferrocenes have been characterized by UV/vis spectroscopy and cyclic voltammetry in dichloromethane. The complexes contain the following ligands: 1-diphenylphosphino- (1), 1-diphenylphosphino-2-methyl- (2), 1-diphenylphosphino-3-methyl- (3), 1-diphenylphosphino-3-trimethylsilyl- (4), 1-diphenylphosphino-2,3-dimethyl- (5), and 1-diphenylphosphino-4,7-dimethyl-indenide (6). The cyclic voltammetry shows an approximately additive relationship between oxidation potential and the type of substituent and its ring position, but with increasing substitution leading to lower than otherwise expected oxidation potentials. The UV/vis spectra show two absorptions with the low energy band moving to lower energy with increasing substitution on the C₅ ring.en
dc.identifier.citationCurnow, O.J., Fern, G.M., Jenkins, E.M. (2006) Electrochemistry and UV/visible spectroscopy of phosphino-substituted bis(η⁵-indenyl)iron(II) complexes. Journal of Organometallic Chemistry, 691(4), pp. 643-647.en
dc.identifier.doihttps://doi.org/10.1016/j.jorganchem.2005.09.044
dc.identifier.issn0022-328X
dc.identifier.urihttp://hdl.handle.net/10092/608
dc.language.isoen
dc.publisherUniversity of Canterbury. Chemistry.en
dc.rights.urihttps://hdl.handle.net/10092/17651en
dc.subjectferroceneen
dc.subjectindenylen
dc.subjectUV/vis spectroscopyen
dc.subjectcyclic voltammetryen
dc.subjectphosphineen
dc.subject.marsdenFields of Research::250000 Chemical Sciences::250300 Organic Chemistry::250301 Organic chemical synthesisen
dc.titleElectrochemistry and UV/visible spectroscopy of phosphino-substituted bis(η⁵-indenyl)iron(II) complexesen
dc.typeJournal Article
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