Synthesis of diisopropylcyclopropenone and X-ray structure of its dichlorodimethyltin(IV) adduct
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Journal Article
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University of Canterbury. Chemistry.
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Date
2006
Authors
Curnow, O.J.
Fern, G.M.
Pipal, R.J.
Abstract
Diisopropylcyclopropenone was prepared by a dehydrobromination of 3,5-dibromo-2,6-dimethylheptan-4-one and isolated in 18% yield via an aqueous extraction procedure. It was characterised by an X-ray crystal structure analysis of its complex with dichlorodimethyltin(IV): Dichlorodimethyl(diisopropylcyclopropenone)tin(IV) was found to have a chloro-bridged dimeric structure in the solid state.
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Citation
Curnow, O.J., Fern, G.M., Pipal, R.J. (2006) Synthesis of diisopropylcyclopropenone and X-ray structure of its dichlorodimethyltin(IV) adduct. ARKIVOC, iii, pp. 43-47.
Keywords
crystal structure, cyclopropenone, tin complex