Engineering multiple topological phases in nanoscale Van der Waals heterostructures: Realisation of α-antimonene (2017)
AuthorsMaerkl T, Kowalczyk PJ, Le Ster M, Mahajan IV, Pirie H, Ahmed Z, Bian G, Wang X, Chiang T-C, Brown SAshow all
Van der Waals heterostructures have recently been identified as providing many opportunities to create new two-dimensional materials, and in particular to produce materials with topologically interesting states. Here we show that it is possible to create such heterostructures with multiple topological phases in a single nanoscale island. We discuss their growth within the framework of diffusion-limited aggregation, the formation of moir\'e patterns due to the differing crystallographies of the materials comprising the heterostructure, and the potential to engineer both the electronic structure as well as local variations of topological order. In particular we show that it is possible to build islands which include both the hexagonal β- and rectangular α-forms of antimonene, on top of the topological insulator α-bismuthene. This is the first experimental realisation of α-antimonene, and we show that it is a topologically non-trivial material in the quantum spin Hall class.
CitationMaerkl T, Kowalczyk PJ, Le Ster M, Mahajan IV, Pirie H, Ahmed Z, Bian G, Wang X, Chiang T-C, Brown SA (2017). Engineering multiple topological phases in nanoscale Van der Waals heterostructures: Realisation of α-antimonene. 2D Materials.
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Keywordscond-mat.mtrl-sci; cond-mat.mtrl-sci; cond-mat.mes-hall; Topological Materials; Antimonene; Bismuth; Nanostructures; 2D Materials; Thin films; Electronic structure
ANZSRC Fields of Research10 - Technology::1007 - Nanotechnology::100708 - Nanomaterials
09 - Engineering::0912 - Materials Engineering::091207 - Metals and Alloy Materials
03 - Chemical Sciences::0303 - Macromolecular and Materials Chemistry::030304 - Physical Chemistry of Materials