Ionic liquid-templated synthesis of 10-MR zeolites and its origin disclosure

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dc.contributor.authorLi, Xuemin
dc.contributor.authorKu, C.
dc.contributor.authorJeong, Y.
dc.contributor.authorCurnow, O.J.
dc.contributor.authorSit, P.H.L.
dc.contributor.authorWu, Z.
dc.contributor.authorChoi, J.
dc.contributor.authorYip, Alex
dc.date.accessioned2020-06-02T00:07:45Z
dc.date.available2020-06-02T00:07:45Z
dc.date.issued2020en
dc.date.updated2020-05-14T21:55:58Z
dc.description.abstractIonic liquids (ILs) have been used as the template/structure-directing agent (SDA) for the synthesis of crystalline materials, including aluminophosphates, metal-organic frameworks (MOFs), and covalent organic frameworks (COFs). This work unravels the structure-directing role of the imidazolium in ILs in 10-membered-ring zeolite synthesis. Herein, we report the key IL structure-dependent parameters affecting the synthesis of TON and MFI zeolites with one-dimensional (1D) and three-dimensional (3D) channel structures, respectively. The imidazolium dictates the resulting zeolite type and the morphologies of the TON and MFI zeolites are predominantly influenced by both the cations and the silica sources. The structure-directing properties of ILs are supported by the lowered energy state determined by density functional theory (DFT) calculations.en
dc.identifier.citationLi X, Ku C, Jeong Y, Curnow O, Sit PHL, Wu Z, Choi J, Yip ACK (2020). Ionic liquid-templated synthesis of 10-MR zeolites and its origin disclosure. Microporous and Mesoporous Materials.en
dc.identifier.issn1387-1811
dc.identifier.urihttps://hdl.handle.net/10092/100178
dc.language.isoen
dc.rightsAll rights reserved unless otherwise stateden
dc.rights.urihttp://hdl.handle.net/10092/17651en
dc.subjectZeoliteen
dc.subjectIonic liquiden
dc.subjectStructural-directingen
dc.subjectHydrothermal synthesisen
dc.subjectMolecular modellingen
dc.subject.anzsrcFields of Research::40 - Engineering::4004 - Chemical engineering::400408 - Reaction engineering (excl. nuclear reactions)en
dc.subject.anzsrcField of Research::03 - Chemical Sciences::0303 - Macromolecular and Materials Chemistry::030306 - Synthesis of Materialsen
dc.titleIonic liquid-templated synthesis of 10-MR zeolites and its origin disclosureen
dc.typeJournal Articleen
uc.collegeFaculty of Engineering
uc.departmentChemical and Process Engineering
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