Sub-μm features patterned with laser interference lithography for the epitaxial lateral overgrowth of α-Ga₂O₃ via mist chemical vapor deposition

Type of content
Journal Article
Thesis discipline
Degree name
Publisher
AIP Publishing
Journal Title
Journal ISSN
Volume Title
Language
en
Date
2021
Authors
Dang, Giang
Yasuoka, T
Kawaharamura, T
Abstract

The low growth rate of mist chemical vapor deposition normally requires a long growth time to achieve coalescence in the epitaxial lateral overgrowth of α-Ga₂O₃ thin films on sapphire substrates. To address this issue, sub-μm features were patterned using laser interference lithography. Periodical stripes with a ∼590-nm pitch allowed the overgrowth of crack-free, void-free, and continuous thin films, while typical growth conditions using a low carrier gas flow rate and a low Ga precursor concentration were maintained. Coalescence was achieved even with a short growth time of <30 min and a low film thickness of <500 nm. Transmittance and x-ray diffraction spectra show that the film was predominantly in α-phase. Transmission electron microscopy (TEM) images reveal cup-top-like α-Ga₂O₃ regions of low dislocation density on the SiOx mask. Selected area electron diffraction and high-resolution TEM analyses confirm that an α-Ga₂O₃ layer was formed even on the top of the SiOx mask. Interestingly, the dislocations formed on the window areas did not bend toward the center of the masks; rather, a dislocation bending outward from the center was observed. This suggests the occurrence of early coalescence and/or atomic rearrangement.

Description
Citation
Dang GT, Yasuoka T, Kawaharamura T (2021). Sub-μm features patterned with laser interference lithography for the epitaxial lateral overgrowth of α-Ga₂O₃ via mist chemical vapor deposition. Applied Physics Letters. 119(4).
Keywords
Ngā upoko tukutuku/Māori subject headings
ANZSRC fields of research
02 Physical Sciences
09 Engineering
10 Technology
51 - Physical sciences
40 - Engineering::4018 - Nanotechnology
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