Reactions of 1,2-epoxyoctane
| dc.contributor.author | Lim, C. E. | en |
| dc.date.accessioned | 2014-06-08T23:18:50Z | |
| dc.date.available | 2014-06-08T23:18:50Z | |
| dc.date.issued | 1975 | en |
| dc.description.abstract | The synthesis of 1,2-epoxyoctane (6) and the stereo-specifically labelled mono and dideuterated derivatives (7) and (8) are described. The BF3 : etherate catalysed rearrangement of 1,2-epoxyoctanes(6), (7) and (8) in ether gave products identified as 1-ethoxy-octan-2-ol (9a), (1S, 2S)1R, 2R-1-d-1-ethoxy-octan-2-ol (10a) and (1R, 2S)1S, 2R-1,2-dideutero-1-ethoxy-octan-2-ol (11a) respectively. The BF3 : etherate catalysed rearrangement of 1,2-epoxyoctane (6) gave aldehyde (14) by selective migration (ca. 1.41 : 1) of the hydrogen atom (Hb) trans to the long chain aliphatic group. | en |
| dc.identifier.uri | http://hdl.handle.net/10092/9247 | |
| dc.identifier.uri | http://dx.doi.org/10.26021/8265 | |
| dc.language.iso | en | |
| dc.publisher | University of Canterbury. Chemistry | en |
| dc.relation.isreferencedby | NZCU | en |
| dc.rights | Copyright C. E. Lim | en |
| dc.rights.uri | https://canterbury.libguides.com/rights/theses | en |
| dc.title | Reactions of 1,2-epoxyoctane | en |
| dc.type | Theses / Dissertations | |
| thesis.degree.discipline | Chemistry | |
| thesis.degree.grantor | University of Canterbury | en |
| thesis.degree.level | Masters | en |
| thesis.degree.name | Master of Science | en |
| uc.bibnumber | 41116 | |
| uc.college | Faculty of Science | en |
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