The simulation of fixed-bed ion exchange columns

dc.contributor.authorAllen, Maurice
dc.date.accessioned2021-06-21T03:51:37Z
dc.date.available2021-06-21T03:51:37Z
dc.date.issued1973en
dc.description.abstractThe equations for the fixed-bed ion exchange process have been rigorously solved to give breakthrough curves using analog, digital and hybrid computers. The models developed for the ion exchange column process are general enough to include:- • Linear and non-linear equilibrium • Constant or variable separation factor • Mass transfer resistance in either the solution or the resin phase, or both • Axial dispersion • General initial conditions for column presaturation • Arbitrary boundary conditions for partial or complete break- through curves. Results indicate that simple rate relations are adequate to express column behaviour for most requirements. In particular, the Thomas model as developed by Hiester and Vermeulen is easy to use and sufficiently accurate for normal applications. A comparison of computed results with experimental data has shown that the ion exchange column process can be accurately simulated. However, this required the use of a variable separation factor for some systems.en
dc.identifier.urihttps://hdl.handle.net/10092/102069
dc.identifier.urihttp://dx.doi.org/10.26021/11124
dc.languageEnglish
dc.language.isoen
dc.publisherUniversity of Canterburyen
dc.rightsAll Right Reserveden
dc.rights.urihttps://canterbury.libguides.com/rights/thesesen
dc.subject.lccFixed bed processes--Computer programsen
dc.subject.lccIon exchange--Computer programs.en
dc.titleThe simulation of fixed-bed ion exchange columnsen
dc.typeTheses / Dissertationsen
thesis.degree.disciplineChemical Engineeringen
thesis.degree.grantorUniversity of Canterburyen
thesis.degree.levelDoctoralen
thesis.degree.nameDoctor of Philosophyen
uc.bibnumber384291en
uc.collegeFaculty of Engineeringen
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