X-ray investigation of structural relationships and physical properties in charge-transfer complexes
| dc.contributor.author | Evans, D. L. | en |
| dc.date.accessioned | 2013-07-29T19:55:46Z | |
| dc.date.available | 2013-07-29T19:55:46Z | |
| dc.date.issued | 1980 | en |
| dc.description.abstract | The crystal structures of four charge-transfer complexes and two organo-metallic compounds have been determined. The various geometries encountered are related to structural isomerism and to physical properties. The charge-transfer complexes phenanthrene pyromellitic acid dianhydride (PMDA), fluorene PMDA, thianthrene PMDA and biphenyl trinitrofluorenone have planar molecules except for thianthrene which is bent. The molecule N-(2-hydroxyphenyl)salicylaldimine dimethyl tin(IV) is bipyramidal whilst the hexa-v-dithiocacodylato tetrazincsulphide isomers have a tetrahedral character. The concept of the crystalline state as a hierarchical system is developed. The physical basis, and electrical properties of charge-transfer complexes are reviewed, and the implications of structural features, and possible uses of these compounds in modern signal processing technology is discussed. | en |
| dc.identifier.uri | http://hdl.handle.net/10092/7971 | |
| dc.identifier.uri | http://dx.doi.org/10.26021/6459 | |
| dc.language.iso | en | |
| dc.publisher | University of Canterbury. Chemistry | en |
| dc.relation.isreferencedby | NZCU | en |
| dc.rights | Copyright D. L. Evans | en |
| dc.rights.uri | https://canterbury.libguides.com/rights/theses | en |
| dc.title | X-ray investigation of structural relationships and physical properties in charge-transfer complexes | en |
| dc.type | Theses / Dissertations | |
| thesis.degree.discipline | Chemistry | en |
| thesis.degree.grantor | University of Canterbury | en |
| thesis.degree.level | Doctoral | en |
| thesis.degree.name | Doctor of Philosophy | en |
| uc.bibnumber | 129767 | en |
| uc.college | Faculty of Science | en |
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