An investigation of the heterogeneous equilibria involved in the systems (a) potassium chloride - mercuric chloride -acetone at 25 degrees C; (b)potassium chloride - mercuric chloride - ethyl alcohol at 25 degrees C; (c) mercuric chloride - acetone - water at 25 degrees C and 35 degrees C (1937)
It has long been realised that the mercuric halides, as salts, possessed remarkable properties. They are readily soluble in non-ionising solvents, have low melting points, and their solutions even in hydroxylic solvents are but feebly ionised. These peculiarities have more recently been attributed to the extreme difficulty with which the two valence electrons are lost by a mercury atom to form an ion.
RightsCopyright G. J. Wilkins
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An investigation into the three component system, zinc oxide, hydrochloric acid, zinc chloride and water Holland, A. C. (University of Canterbury. Chemistry, 1928)Zinc Hydrogen or oxide is soluble in an aqueous solution of zinc chloride, and when a concentrated solution is diluted with water, a basic salt, an oxychloride of zinc is precipitated. The Formation of zinc oxychloride is ...
Investigations on the heterogenous systems : (1) lead acetate - ammonium acetate - acetic acid at 25 °C : (2) lead oxide - hydrochloric acid - water at 50 °C and 80 °C. Wilkinson, L. (University of Canterbury. Chemistry, 1936)There have been no isothermic phase-rule studies on acetic acid, as a single solvent, reported in the literature; though Davidson ad co-workers have studied many binary and several ternary systems by the synthetic or ...
Phase rule investigations of the three component systems phenol-water-salt at 25 degrees centigrade Brown, N. A. (University of Canterbury. Chemistry, 1937)The phenol – water systems and the effect of the addition of a third component on the mutual solubilities have been the subject of much investigation during the last twenty or thirty years. The aspect usually considered ...