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    Rates of reaction of benzylamines with 1-chloro 2.4-dinitrobenzene

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    Author
    Hickford, R. S. H.
    Date
    1963
    Permanent Link
    http://hdl.handle.net/10092/8646
    Thesis Discipline
    Chemistry
    Degree Grantor
    University of Canterbury
    Degree Level
    Masters
    Degree Name
    Master of Science

    Several meta and para substituted benzylamines have been prepared. The rates of reaction of benzylamine and fourteen substituted benzylamines with 1-chloro 2,4-dinitrobenzene in ethanol have been measured. The kinetics were followed by using an acid-base titration method to determine the amount of benzylamine in the reaction mixture at intervals. The logarithms of the rate constants correlate with Taft's σ° constants within the precision of the latter.

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