Dimensional changes in porous solids during gas adsorption

Type of content
Theses / Dissertations
Publisher's DOI/URI
Thesis discipline
Chemistry
Degree name
Doctor of Philosophy
Publisher
University of Canterbury. Chemistry
Journal Title
Journal ISSN
Volume Title
Language
Date
1973
Authors
Wilcock, R. J.
Abstract

An experimental method of observing adsorptive length changes in porpoise rods by means of a linear differential transformer and inductance bridge has been developed. The method was used to observe the adsorptive length change behaviour of rods of kaolinite and Vycor, when they were exposed to the vapours of H₂O, CH₃OH, C₂H₅OH, CHCl₃, CCl₄, and C₆H₆. Spreading pressure – length change slopes were measured and the variation in their values for a solid at a particular temperature discussed in terms of the structures of the absorbed phases. An attempt was made to measure the strength of the adsorbate-adsorbent and adsorbate-adsorbate interactions thermodynamically, using the BET c parameter. The effect of particle alignment during extrusion in kaolinite rods was studies by means of ultrasonic and x-ray diffraction techniques.

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Copyright R. J. Wilcock