The first metal complexes of 3,3'-bi-1,2,4-oxadiazole: A curiously ignored ligand (2007)
AuthorsRichardson, C., Steel, P.J.show all
The crystal structure of 3,3'-bi-1,2,4-oxadiazole (1) reveals a planar centrosymmetric structure for this molecule in the solid state. It forms a mononuclear complex (3) with palladium(II) chloride, which is shown by X-ray crystallography to contain the ligand chelated through the two N4 nitrogens. The X-ray structure of the complex (5) with silver(I) nitrate shows a one-dimensional coordination polymer in which the ligand acts in a bridging mode, again with coordination through the N4 nitrogen atoms.
CitationRichardson, C., Steel, P.J. (2007) The first metal complexes of 3,3'-bi-1,2,4-oxadiazole: A curiously ignored ligand. Inorganic Chemistry Communications, 10(8), pp. 884-887.
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