Tropospheric Ozone at Northern Mid-Latitudes: Modeled and Measured Long-Term Changes (2017)
In this paper, we investigate why current state-of-the-art chemistry-climate models underestimate the tropospheric ozone increase from the 1950s to the 1990s by approximately 50%. The accuracy of these models is vital, not only for understanding and predicting air quality globally, but also since they are used to quantify the contribution of ozone in the troposphere and lower stratosphere to climate change, where its greenhouse effect is largest. We briefly describe available northern mid-latitude ozone measurements, which include representative and reliable data from European sites that extend back to the 1950s. We use the SOCOLv3 (Solar Climate Ozone Links version 3) global chemistry-climate model to investigate the individual terms of the tropospheric ozone budget. These include: inflow from the stratosphere, dry deposition, and chemical formation and destruction. For 1960 to 2000 SOCOLv3 indicates a tropospheric ozone increase at 850 hPa over the Swiss Alps (Arosa) of 17 ppb, or around 30%. This increase is smaller than that seen in the surface ozone measurements but similar to other chemistry-climate models, including those with more complex NMVOC (Non Methane Volatile Organic Compound) schemes than SOCOLv3’s. It is likely that the underestimated increase in tropospheric ozone could be explained by issues in the underlying emissions inventories used in the model simulations, with ozone precursor emissions, particularly NOx (NO + NO2), from the 1960s being too large.
Keywordsozone; troposphere; climate change; long-term ozone changes; model evaluation; SOCOL
ANZSRC Fields of Research04 - Earth Sciences::0401 - Atmospheric Sciences::040108 - Tropospheric and Stratospheric Physics
04 - Earth Sciences::0401 - Atmospheric Sciences::040104 - Climate Change Processes
Rights© 2017 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
Showing items related by title, author, creator and subject.
Tropospheric jet response to Antarctic ozone depletion: An update with Chemistry-Climate Model Initiative (CCMI) models Son S-W; Han B-R; Garfinkel CI; Kim S-Y; Park R; Abraham NL; Akiyoshi H; Archibald AT; Butchart N; Chipperfield M; Dameris M; Deushi M; Dhomse S; Hardiman SC; Jockel P; Kinnison D; Michou M; Morgenstern O; O'Connor FM; Oman L; Plummer D; Pozzer A; Revell LE; Rozanov E; Stenke A; Stone K; Tilmes S; Yamashita Y; Zeng G (2018)The Southern Hemisphere (SH) zonal-mean circulation change in response to Antarctic ozone depletion is re-visited by examining a set of the latest model simulations archived for the Chemistry-Climate Model Initiative ...
Attribution of Chemistry-Climate Model Initiative (CCMI) ozone radiative flux bias from satellites Kuai L; Bowman KW; Miyazaki K; Deushi M; Revell L; Rozanov E; Paulot F; Strode S; Conley A; Lamarque J-F; Jöckel P; Plummer DA; Oman LD; Worden H; Kulawik S; Paynter D; Stenke A; Kunze M (Copernicus GmbH, 2020)The top-of-atmosphere (TOA) outgoing longwave flux over the 9.6 µm ozone band is a fundamental quantity for understanding chemistry–climate coupling. However, observed TOA fluxes are hard to estimate as they exhibit c ...
No robust evidence of future changes in major stratospheric sudden warmings: a multi-model assessment from CCMI Ayarzaguena B; Polvani LM; Langematz U; Akiyoshi H; Bekki S; Butchart N; Dameris M; Deushi M; Hardiman SC; Jockel P; Klekociuk A; Marchand M; Michou M; Morgenstern O; O'Connor F; Oman LD; Plummer DA; Revell LE; Rozanov E; Saint-Martin D; Scinocca J; Stenke A; Stone K; Yamashita Y; Yoshida K; Zeng G (2018)Major mid-winter stratospheric sudden warmings (SSWs) are the largest instance of wintertime variability in the Arctic stratosphere. Because SSWs are able to cause significant surface weather anomalies on intra-season ...