Variation of guest selectivity within [Fe₄L₄]⁸⁺ tetrahedral cages through subtle modification of the face-capping ligand (2014)
Type of ContentJournal Article
PublisherUniversity of Canterbury. Chemistry
- Science: Journal Articles 
We report here the host–guest behaviour of two isoelectronic [Fe₄L₄]⁸⁺ tetrahedral cages that differ only in the nature of their face-capping ligand and possess either triazine (L1) or benzene (L2) cores. Crystallography reveals these hosts to be flexible and adaptable, while NMR spectroscopy shows them to be selective and discriminating in their host–guest behaviour.
CitationFerguson, A., Staniland, R.W., Fitchett, C.M., Squire, M.A., Williamson, B.E., Kruger, P.E. (2014) Variation of guest selectivity within [Fe₄L₄]⁸⁺ tetrahedral cages through subtle modification of the face-capping ligand. Dalton Transactions, 43, pp. 14550-14553.
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ANZSRC Fields of Research03 - Chemical Sciences::0303 - Macromolecular and Materials Chemistry::030302 - Nanochemistry and Supramolecular Chemistry
03 - Chemical Sciences::0303 - Macromolecular and Materials Chemistry::030306 - Synthesis of Materials
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