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    Variation of guest selectivity within [Fe₄L₄]⁸⁺ tetrahedral cages through subtle modification of the face-capping ligand (2014)

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    12651825_Dalton Transactions, 2014, 43, 14550-14553.pdf (548.9Kb)
    Type of Content
    Journal Article
    UC Permalink
    http://hdl.handle.net/10092/10012
    
    Publisher's DOI/URI
    https://doi.org/10.1039/c4dt02337d
    
    Publisher
    University of Canterbury. Chemistry
    Collections
    • Science: Journal Articles [1099]
    Authors
    Ferguson, A.
    Staniland, R.W.
    Fitchett, C.M.
    Squire, M.A.
    Williamson, B.E.
    Kruger, P.E.
    show all
    Abstract

    We report here the host–guest behaviour of two isoelectronic [Fe₄L₄]⁸⁺ tetrahedral cages that differ only in the nature of their face-capping ligand and possess either triazine (L1) or benzene (L2) cores. Crystallography reveals these hosts to be flexible and adaptable, while NMR spectroscopy shows them to be selective and discriminating in their host–guest behaviour.

    Citation
    Ferguson, A., Staniland, R.W., Fitchett, C.M., Squire, M.A., Williamson, B.E., Kruger, P.E. (2014) Variation of guest selectivity within [Fe₄L₄]⁸⁺ tetrahedral cages through subtle modification of the face-capping ligand. Dalton Transactions, 43, pp. 14550-14553.
    This citation is automatically generated and may be unreliable. Use as a guide only.
    ANZSRC Fields of Research
    03 - Chemical Sciences::0303 - Macromolecular and Materials Chemistry::030302 - Nanochemistry and Supramolecular Chemistry
    03 - Chemical Sciences::0303 - Macromolecular and Materials Chemistry::030306 - Synthesis of Materials
    Rights
    https://hdl.handle.net/10092/17651

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